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NEET2006ChemistryGeneral Organic ChemistryActual

Assertion : Anilinium chloride is more acidic than ammonium chloride. Reason : Anilinium ion is resonance-stabilised.

Options

  1. AIf both assertion and reason are true and reason is the correct explanation of the assertion
  2. BIf both assertion and reason are true but reason is not the correct explanation of the assertion
  3. CIf assertion is true, but reason is false
  4. DBoth assertion and reason are false statements.

Correct answer

C. If assertion is true, but reason is false

Step-by-step solution

Aniline is weaker base than ammonium chloride. In NH ₄ Cl or aliphatic amines, the non-bonding electron pair of N is localized and is fully available for coordination with a proton. On the other hand, in aniline or other aromatic amines, the non-bonding electron pair is delocalised into benzene ring by resonance.

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