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NEET2005ChemistryGeneral Organic ChemistryActual

Which carbocation is most stable?

Options

  1. ACH ₃ CH ₂⁺
  2. BCH ₃⁺
  3. CC ₆ H ₅ CH ₂⁺
  4. DCH ₃ CH ₂ CH ₂⁺

Correct answer

C. C ₆ H ₅ CH ₂⁺

Step-by-step solution

A phenyl group, in which there is a flow of electron due to resonance of the benzene ring, generally causes -I effect, but truely speaking it can act as both electron donating as well as electron withdrawing groups, depending upon the nature of group with which it is attached. In C ₆ H ₅ CH ₂⁺ , phenyl group is attached to electron deficient group, hence it will donate electron due to resonance in benzene ring and thus stabilise the cation.

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