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NEETChemistryp Block Elements (Group 15, 16, 17 & 18)

Read the following statements carefully: Statement I: XeF ₂ is a linear molecule with three lone pairs of electrons at equatorial positions. Statement II: ClF ₃ has a T-shape with two lone pairs of electrons at axial positions. Statement III: XeF ₆ has a distorted octahedral shape and sp ^3 d ^3 hybridization. Statement IV: BrF ₅ has a square planar geometry with one lone pair. How many of the given statements are co

Options

  1. AOnly two
  2. BOnly one
  3. COnly three
  4. DAll four

Correct answer

A. Only two

Step-by-step solution

Statement I is correct: In XeF ₂ , the central Xe atom has 8 valence electrons. It forms 2 single bonds with F atoms, leaving 3 lone pairs. The hybridization is sp ^3 d . To minimize repulsion, the three lone pairs occupy the equatorial positions, resulting in a linear shape. Statement II is incorrect: In ClF ₃ , the central Cl atom is sp ^3 d hybridized with 3 bond pairs and 2 lone pairs. The lone pairs occupy equatorial positions (not axial) to minimize lone pair-lone pair repulsions, giving it a T-shape. Stateme

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