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NEETChemistryp Block Elements (Group 15, 16, 17 & 18)

Gas X is produced commercially by Deacon's process. When gas X reacts with dry slaked lime, it gives a compound Y which is widely used as a bleaching agent. Identify gas X and the active bleaching ion present in compound Y.

Options

  1. AHCl and Cl ^-
  2. BCl ₂ and Cl ^-
  3. CO ₂ and O ₂²⁻
  4. DCl ₂ and ClO ^-

Correct answer

D. Cl ₂ and ClO ^-

Step-by-step solution

Gas X is chlorine ( Cl ₂ ), which is manufactured commercially by Deacon's process. This process involves the oxidation of hydrogen chloride gas by atmospheric oxygen in the presence of a CuCl ₂ catalyst. Chlorine reacts with dry slaked lime ( Ca(OH) ₂ ) to produce bleaching powder. The reaction is: 2 Ca(OH) ₂ + 2 Cl ₂ Ca(OCl) ₂ + CaCl ₂ + 2 H ₂ O The composition of bleaching powder is represented as Ca(OCl) ₂ CaCl ₂ Ca(OH) ₂ 2 H ₂ O . The active bleaching agent in it is the hypochlorite ion ( ClO ^- or OCl ^- ). A

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