NEETChemistryp Block Elements (Group 15, 16, 17 & 18)
Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Fluorine is a stronger oxidising agent than chlorine despite having a less negative electron gain enthalpy. Reason (R): Fluorine does not exhibit any positive oxidation state in its compounds. In the light of the above statements, choose the most appropriate answer from the options given below:
Options
- ABoth Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A).
- BBoth Assertion (A) and Reason (R) are true and Reason (R) is not the correct explanation of Assertion (A).
- CAssertion (A) is true but Reason (R) is false.
- DAssertion (A) is false but Reason (R) is true.
Correct answer
B. Both Assertion (A) and Reason (R) are true and Reason (R) is not the correct explanation of Assertion (A).
Step-by-step solution
Assertion (A) is true: Fluorine is the strongest oxidising agent among halogens. Its standard reduction potential is the highest, making it a stronger oxidising agent than chlorine, even though its electron gain enthalpy is less negative than that of chlorine. Reason (R) is true: Fluorine is the most electronegative element and lacks vacant d-orbitals in its valence shell, so it exhibits only a -1 oxidation state and never a positive oxidation state. However, Reason (R) does not explain Assertion (A). The correct e