NEET2017Chemistryp Block Elements (Group 15, 16, 17 & 18)Actual
Sulphur reacts with chlorine in 1: 2 ratio and forms X . Hydrolysis of X gives a sulphur compound Y . The hydridisation of central atom in the anion Y is
Options
- As p^3
- Bs p^2
- Cs p^3 d
- Ds p
Correct answer
A. s p^3
Step-by-step solution
When sulphur reacts with chlorine in 1: 2 ratio the SCl ₄ is obtained which on hydrolysis gives H ₂ SO ₄ . Hence, the compound ' X ' is SCl ₄ and ' Y ' is H ₂ SO ₄ SCl ₄+4 H ₂ O Unstable S ( OH )₄ +4 HCl S ( OH )₄ Sulphurous acid H ₂ SO ₄ + H ₂ O The hybridisation of sulphur in SO ₃²⁻ is s p^3 .