NEETChemistryAlcohols Phenols and Ethers
Explain why is ortho nitrophenol more acidic than ortho methoxyphenol?
Options
- AOrtho-nitrophenol has a larger molecular size, leading to greater acidity.
- Bbecause o-nitrophenoxide ion is stabilized due to resonance. This is not true with o-methoxyphenoxide ion. The
- COrtho-methoxyphenol has a more electronegative substituent, making it less acidic.
- DOrtho-methoxyphenol forms stronger hydrogen bonds with water molecules.
Correct answer
B. because o-nitrophenoxide ion is stabilized due to resonance. This is not true with o-methoxyphenoxide ion. The
Step-by-step solution
Correct Option is : (B) because o-nitrophenoxide ion is stabilized due to resonance. This is not true with o-methoxyphenoxide ion. The two negative charges repel each other thereby destabilizing it.