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NEET Alcohols Phenols and Ethers PYQs with Solutions

655 previous year questions from Alcohols Phenols and Ethers (NEET UG Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

655 questionsChemistry2004–2026Answers + solutions

About Alcohols Phenols and Ethers PYQs

Alcohols Phenols and Ethers has 655 previous year questions in the Quantrex Academy NEET UG Chemistry bank. The 220 questions in this list come from NEET (158), MHT CET Medical (31) and JIPMER (31), spanning 2004 to 2026. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2026: 31
  • 2019: 2
  • 2018: 4
  • 2017: 4
  • 2016: 1
  • 2015: 1
  • 2014: 1
  • 2012: 1
  • 2011: 1
  • 2010: 2
  • 2009: 2
  • 2008: 5

Alcohols Phenols and Ethers questions with solutions

1

Identify the product formed when ethyl alcohol reacts with H_2SO_4 at 443 K.

MHT CET Medical 2026 Solution
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2

Identify the product obtained when phenol reacts with bromine in presence of CS_2

MHT CET Medical 2026 Solution
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3

Which is the Lucas reagent among following?

MHT CET Medical 2026 Solution
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4

Identify the type of the following reaction?

MHT CET Medical 2026 Solution
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5

Identify the compounds formed when anisole is heated with concentrated HI.

MHT CET Medical 2026 Solution
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6

Identify the product of Kolbe's reaction from following.

MHT CET Medical 2026 Solution
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7

Identify the product formed when the mixture of Phenol and Hydrogen is passed over nickel catalyst at 433 K.

MHT CET Medical 2026 Solution
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8

Which of the following compounds is found in Indian gooseberry?

MHT CET Medical 2026 Solution
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9

Butan-2-ol is heated with red phosphorous and bromine. Find the number of optical isomers of the product formed.

MHT CET Medical 2026 Solution
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10

An organic compound A on reaction with thionyl chloride, gives compound B. Compound B, reacts with sodium in dry ether as solvent, gives 2,3-dimethyl butane. Identify compound A.

MHT CET Medical 2026 Solution
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11

Which of following reagents convert propene to 1-propanol?

MHT CET Medical 2026 Solution
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12

Identify the product when propan-2-ol heated with Cu at 573 K.

MHT CET Medical 2026 Solution
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13

An organic compound 'A' on oxidation with pyridinium chlorochromate forms an aldehyde having the molecular formula C_2H_4O . What is compound 'A'?

MHT CET Medical 2026 Solution
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14

What is the product formed on the reduction of carboxylic acids using lithium aluminum hydride?

MHT CET Medical 2026 Solution
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15

Which of the following compounds, when treated with acetic anhydride, forms aspirin?

MHT CET Medical 2026 Solution
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16

Identify the substrate 'S' in the following reaction.

MHT CET Medical 2026 Solution
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17

What is the common name of benzene-1,2,3-triol?:

MHT CET Medical 2026 Solution
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18

Vapours of alcohol are passed over hot copper to give ketone. Ketone reacts with ethylene glycol to give a cyclic ketal. Cyclic ketal by treating with aq. HCl forms acetone.

MHT CET Medical 2026 Solution
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19

Which of the following reagents is used to distinguish ethers from hydrocarbons?

MHT CET Medical 2026 Solution
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20

Identify Lucas reagent from following.

MHT CET Medical 2026 Solution
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21

Which of the following reagent is used to convert alkene to alcohol through hydration ?

MHT CET Medical 2026 Solution
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22

Identify the reagent used in Reimer-Tiemann reaction,

MHT CET Medical 2026 Solution
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23

Identify A, B and C in following reaction when phenol is treated with chloroform in presence of NaOH?

MHT CET Medical 2026 Solution
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24

Identify the amount of Dihydrogen formed when 46\ g Na (molar mass = 23\ g mol^ -1 ) reacts with excess ethanol.

MHT CET Medical 2026 Solution
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25

Name the following reaction.

MHT CET Medical 2026 Solution
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26

Identify the name of CH_3CH_2OH according to carbinol system.

MHT CET Medical 2026 Solution
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27

Which of the following reactions is used to prepare salicylaldehyde from phenol ?

MHT CET Medical 2026 Solution
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28

In the given reaction, the product "Z" is - CH_3-CH(OH)-CH_3 Cu / 573 K . oxidation Z

MHT CET Medical 2026 Solution
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29

Which of the following reagents is used for converting alcohol to alkyl chloride?

MHT CET Medical 2026 Solution
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30

Phenols react with neutral ferric chloride, then which coloration is NOT produced?

MHT CET Medical 2026 Solution
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31

What is the trivial name of Ethane 1,2-di-ol?

MHT CET Medical 2026 Solution
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32

The main product obtained from phenol with PCl_5 is

JIPMER 2019 Solution
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33

array r CH_3-CH_2-CH=CH_2 X CH_3 CH_2-CH_2-CH_2 OH array What is suitable reagent (X) ?

JIPMER 2019 Solution
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34

What is the product ' P ' is the above reaction?

JIPMER 2018 Solution
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35

Which of the following is the correct sequence of step involved in the mechanism of Cannizzaro reaction?

JIPMER 2018 Solution
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36

Identify the major product that is obtained on treatment of CH_3 CH_2 CH(F) CH_3 with CH_3 O^ - / CH_3 OH is

JIPMER 2018 Solution
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37

When phenol is treated with CHCl_3 and NaOH followed by acidification, salicylaldehyde is obtained. Which of the following species is involved in the above mentioned reaction as

JIPMER 2018 Solution
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38

Iso-propyl chloride +A Δ 2-ethoxy propane +NaCl . The compound (A) is

JIPMER 2017 Solution
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39

Aqueous 10 \% NaHCO_3 solution is used as a reagent for identifying ' A '. Which of the following compounds yield ' A ' on hydrolysis?

JIPMER 2017 Solution
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40

Phenol [ (ii) CO_2 / 140^ ∘ C] (i) NaOH A H^ + / H_2 O B Ac_2 O C In the above reaction, end product ‘C’ is

JIPMER 2017 Solution
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41

The product (P) is

JIPMER 2017 Solution
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42

Ethers like ROR can be cleaved by concentrated HI but not by HCl because

JIPMER 2016 Solution
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43

The product P of the given reaction is

JIPMER 2015 Solution
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44

Which of the following compounds is soluble in benzene but almost insoluble in water?

JIPMER 2014 Solution
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45

On warming with silver powder, chloroform is converted into

JIPMER 2012 Solution
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46

The compound which forms acetaldehyde when heated with dilute NaOH , is

JIPMER 2011 Solution
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47

Primary alcohols can be obtained from the reaction of R Mg X with

JIPMER 2010 Solution
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48

Ethyl alcohol reacts with thionyl chloride to give

JIPMER 2010 Solution
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49

Which of the following can give a Grignard reagent when reacted with magnesium in dry ether ?

JIPMER 2009 Solution
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50

Which is used in alcoholic beverages ?

JIPMER 2009 Solution
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51

A fruity smell is produced by the reaction of \(C_2 H_5 OH\) with

JIPMER 2008 Solution
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52

Hydrolysis of phenyl isocyanide forms

JIPMER 2008 Solution
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53

Reaction of ethyl formate with excess of \(CH_3 MgI\) followed by hydrolysis gives

JIPMER 2008 Solution
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54

Methanol and ethanol are miscible in water due to

JIPMER 2008 Solution
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55

The product of following reaction is \(2 CH_3 MgBr+CH_2 O \)

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56

Which one of the following compounds is most acidic?

JIPMER 2007 Solution
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57

In Williamson's synthesis, ethoxyethane is prepared by :

JIPMER 2006 Solution
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58

HCHO reacts with CH_3 MgI to give :

JIPMER 2006 Solution
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59

Phenol reacts with chloroform in presence of

JIPMER 2005 Solution
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60

Which of the following compound gives iodoform test?

JIPMER 2005 Solution
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61

NaOH / H^ + reacts with

JIPMER 2005 Solution
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62

The compound which reacts faster with Lucas reagent is

JIPMER 2004 Solution
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63

Which rule dictates the regioselectivity of the addition reaction of unsymmetrical alkenes in acid-catalysed hydration?

NEET Solution
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64

What electrophile reacts with the phenoxide ion to form ortho hydroxybenzoic acid?

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65

Which of the following alcohols is most likely to undergo dehydrogenation to form an alkene?

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66

What is the product of the reaction between acetone and a Grignard reagent?

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67

What is the final step in the synthesis of phenol from benzene sulphonic acid?

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68

Which type of alcohol is most reactive as a nucleophile in nucleophilic substitution reactions?

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69

Which type of alkyl group is suitable for the preparation of ethers via bimolecular dehydration?

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70

What is the order of reactivity of hydrogen halides in the cleavage of ethers?

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71

Which positions in the benzene ring are favoured for electrophilic substitution due to the presence of the -OH group?

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72

How does the presence of an aromatic ring affect the properties of phenols?

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73

What is the primary purpose of a protic acid in alcohol dehydration reactions?

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74

In the order of ease of dehydration, which type of alcohol is the easiest to dehydrate?

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75

What is the first step in the reaction of Grignard reagents with aldehydes and ketones?

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76

Why are ethers less soluble in water compared to alcohols of similar molecular masses?

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77

What is the general trend in the acid strength of alcohols when electron-releasing groups are attached to the alkyl chain?

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78

In the Reimer-Tiemann reaction, what happens to the benzal chloride intermediate to produce salicylaldehyde?

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79

In the presence of air, what do phenols slowly oxidise to, leading to dark-coloured mixtures?

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80

Which functional group is formed when an alcohol reacts with an alkyl halide in a nucleophilic substitution reaction?

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81

What does the formation of turbidity in the Lucas test indicate?

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82

Which type of alcohol is the most challenging to dehydrate among primary, secondary, and tertiary alcohols?

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83

What is the purpose of sodium hydroxide (NaOH) in the Reimer-Tiemann reaction?

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84

What is the primary purpose of the oleum in the synthesis of phenol from benzene?

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85

What type of reaction is the conversion of phenol to phenol-2,4-disulphonic acid with concentrated sulfuric acid?

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86

What type of alcohol is produced when methanal (formaldehyde) reacts with a Grignard reagent?

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87

As the size of alkyl/aryl groups in alcohols increases, their solubility in water generally:

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88

Why do the boiling points of alcohol decrease with an increase in branching in the carbon chain?

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89

Which acid is typically used for treating cumene hydroperoxide to produce phenol and acetone?

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90

What is the role of concentrated hydrogen halides in the cleavage of ethers?

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91

Which type of alcohol reacts most readily with a given haloacid?

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92

What product is obtained when phenol reacts with concentrated nitric acid?

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93

At what temperature is ethoxyethane the main product of ethanol dehydration in the presence of sulfuric acid?

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94

In the acid-catalysed hydration of alkenes, what is the role of the acid catalyst?

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95

What is the electron-rich nature of ortho and para positions in phenols attributed to?

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96

How can ortho and para nitrophenols be separated?

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97

Under what conditions does bimolecular dehydration favour the formation of alkenes over ethers?

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98

In the mechanism of acid-catalysed hydration, what is formed when protonation of alkene occurs?

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99

When a ketone reacts with a Grignard reagent, what type of bond forms between the carbon atoms of the two reactants?

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100

What is the purpose of deprotonation in the acid-catalysed hydration mechanism?

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101

In the reaction between water and an alkoxide, what role does water play?

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102

Which of the following is a potential side reaction in the Williamson ether synthesis when using secondary or tertiary alkyl halides?

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103

Why is p-nitrophenol less volatile than o-nitrophenol?

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104

What is the main feature of oxidation reactions of alcohols?

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105

Which type of carbon-carbon bond is formed in the hydroboration step of the reaction?

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106

Why is lithium aluminium hydride considered an expensive reagent?

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107

Which factor primarily determines the nucleophilic reactivity of alcohols?

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108

What type of reaction do alcohols typically undergo when they act as nucleophiles?

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109

Why is bromination of anisole an important reaction in organic chemistry?

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110

How are alkyl aryl ethers cleaved, and what products are formed?

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111

Which factor plays a crucial role in determining whether an alcohol undergoes substitution or elimination during dehydration?

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112

What is the main product when a tertiary alkyl halide reacts with CH 3 ONa in the Williamson ether synthesis?

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113

What type of bond is broken during the dehydration of alcohol?

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114

Why does the -OH group attached to the benzene ring activate it towards electrophilic substitution?

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115

How is sodium phenoxide formed from benzene sulphonic acid?

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116

What is the main product when a tertiary alkyl halide reacts with CH3ONa in the Williamson ether synthesis?

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117

Why are alkoxides capable of promoting elimination reactions in addition to substitution reactions in the Williamson ether synthesis?

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118

Which of the following statements is true about the reaction of phenol with zinc dust?

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119

What is the intermediate product formed after the reaction of phenol with chloroform in the Reimer-Tiemann reaction?

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120

Which of the following alcohols is likely to be miscible with water in all proportions?

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