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MHT CET 202625 AprilMorning Shift
Exam
MHT CET
Year
2026
Date
25 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

MHT CET 2026 · 25 April · Morning Shift · Chemistry · Alcohols Phenols and Ethers

Identify the product obtained when phenol reacts with bromine in...

Identify the product obtained when phenol reacts with bromine in presence of CS2\text{CS}_2

Options

  1. AP-Bromophenol
  2. BMixture of O-Bromophenol and P-Bromophenol
  3. C2, 4, 6-tribromophenol
  4. Dm-Bromophenol

Correct answer

B. Mixture of O-Bromophenol and P-Bromophenol

Step-by-step solution

Phenol reacts with bromine in the presence of a non-polar solvent such as CS2\text{CS}_2 or CHCl3\text{CHCl}_3 at low temperature to undergo electrophilic aromatic substitution.

In a non-polar solvent, the ionization of phenol is suppressed, and the electrophile Br+\text{Br}^+ is generated in a smaller concentration compared to the reaction in a polar solvent like water. This prevents polyhalogenation.

As a result, mono-bromination takes place, yielding a mixture of ortho-bromophenol (minor product) and para-bromophenol (major product).

Therefore, the product obtained is a mixture of O-Bromophenol and P-Bromophenol.

Answer: Mixture of O-Bromophenol and P-Bromophenol
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