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NEETChemistryAlcohols Phenols and Ethers

What are the limitations of Williamson synthesis for the preparation of certain types of ethers?

Options

  1. AWilliamson synthesis cannot be used for the preparation of symmetrical ethers.
  2. BIn Williamson's synthesis reaction for the preparation of ether, the alkyl halide used must be primary as tert
  3. CWilliamson synthesis cannot be used for the preparation of unsymmetrical ethers.
  4. DWilliamson synthesis is limited to the preparation of ethers with low molecular weights.

Correct answer

B. In Williamson's synthesis reaction for the preparation of ether, the alkyl halide used must be primary as tert

Step-by-step solution

Correct Option is : (B) In Williamson's synthesis reaction for the preparation of ether, the alkyl halide used must be primary as tertiary halides readily undergo elimination with strong bases like C 2 H 5 ONa.

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