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NEETChemistryAlcohols Phenols and Ethers

Explain why p-nitrophenol is more acidic than phenol.

Options

  1. AThe presence of an electron-withdrawing group, the -NO 2 group,improves the acidic strength of p-nitrophenol b
  2. Bp-Nitrophenol has a higher molecular weight than phenol.
  3. Cp-Nitrophenol has a lower molecular weight than phenol.
  4. DThe presence of a nitro group in p-nitrophenol destabilizes the phenoxide ion formed during deprotonation.

Correct answer

A. The presence of an electron-withdrawing group, the -NO 2 group,improves the acidic strength of p-nitrophenol b

Step-by-step solution

Correct Option is : (A) The presence of an electron-withdrawing group, the -NO 2 group,improves the acidic strength of p-nitrophenol by stabilizing the phenoxide ion, hence para-nitrophenol is more acidic than phenol.

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