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NEETChemistryAlcohols Phenols and Ethers

An unknown alcohol with the molecular formula C ₄ H ₁₀ O is treated with Lucas reagent at room temperature. It produces turbidity immediately. The IUPAC name of the unknown alcohol is:

Options

  1. A2-Methylpropan-2-ol
  2. BButan-2-ol
  3. CButan-1-ol
  4. D2-Methylpropan-1-ol

Correct answer

A. 2-Methylpropan-2-ol

Step-by-step solution

The Lucas test is used to distinguish primary, secondary, and tertiary alcohols. The reagent is a mixture of concentrated HCl and anhydrous ZnCl ₂ . The formation of turbidity is due to the formation of an insoluble alkyl chloride. Tertiary alcohols react immediately to form turbidity, secondary alcohols take about 5 minutes, and primary alcohols do not produce turbidity at room temperature. Since the unknown alcohol ( C ₄ H ₁₀ O ) produces turbidity immediately, it must be a tertiary alcohol. Among the structural

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