NEET2019ChemistryAlcohols Phenols and EthersActual
The main product obtained from phenol with PCl ₅ is
Options
- ABHC
- Bhexachlorobenzene
- Cchlorobenzene
- Dtriphenyl phosphate
Correct answer
D. triphenyl phosphate
Step-by-step solution
The reaction of phenol with PCl ₅ is as follows aligned & 3 C ₆ H ₅ OH + POCl ₃ Triphenyl phosphate ( C ₆ H ₅ )₃ PO ₄+3 HCl & aligned The yield of chlorobenzene in the above reaction is very poor. Thus, the main product of the reaction is triphenyl phosphate ( C ₆ H ₅ )₃ PO ₄ .