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NEET2019ChemistryAlcohols Phenols and EthersActual

The main product obtained from phenol with PCl ₅ is

Options

  1. ABHC
  2. Bhexachlorobenzene
  3. Cchlorobenzene
  4. Dtriphenyl phosphate

Correct answer

D. triphenyl phosphate

Step-by-step solution

The reaction of phenol with PCl ₅ is as follows aligned & 3 C ₆ H ₅ OH + POCl ₃ Triphenyl phosphate ( C ₆ H ₅ )₃ PO ₄+3 HCl & aligned The yield of chlorobenzene in the above reaction is very poor. Thus, the main product of the reaction is triphenyl phosphate ( C ₆ H ₅ )₃ PO ₄ .

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