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NEETChemistryAldehydes and Ketones

Why are carboxylic acids more acidic than alcohols or phenols although all of them have a hydrogen atom attached to an oxygen atom (—O—H)?

Options

  1. ACarboxylic acids have a larger atomic radius, leading to stronger hydrogen bonding.
  2. BCarboxylic acids contain a carbonyl group, making them more susceptible to nucleophilic attack.
  3. CThe conjugate base of carboxylic acid, a carboxylate ion, is stabilized by two equivalent resonance structures
  4. DAlcohols and phenols have a more stable conjugate base, reducing their acidity.

Correct answer

C. The conjugate base of carboxylic acid, a carboxylate ion, is stabilized by two equivalent resonance structures

Step-by-step solution

Correct Option is : (C) The conjugate base of carboxylic acid, a carboxylate ion, is stabilized by two equivalent resonance structures in which the negative charge is at the more electronegative oxygen atom . The conjugate base of phenoxide ion, has non-equivalent resonance

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