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NEETChemistryAldehydes and Ketones

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): The reaction of propanone with dilute Ba(OH) ₂ at room temperature yields a ketol, whereas heating the reaction mixture yields an , -unsaturated ketone. Reason (R): -hydroxy ketones readily undergo dehydration on heating because the resulting carbon-carbon double bond is isolated from the carbonyl

Options

  1. ABoth Assertion and Reason are correct and Reason is the correct explanation for Assertion.
  2. BBoth Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
  3. CAssertion is correct but Reason is incorrect.
  4. DAssertion is incorrect but Reason is correct.

Correct answer

C. Assertion is correct but Reason is incorrect.

Step-by-step solution

Assertion (A) is correct: Propanone reacts with dilute Ba(OH) ₂ at room temperature to form a -hydroxy ketone (ketol), specifically 4-hydroxy-4-methylpentan-2-one. Upon heating, this ketol readily undergoes dehydration to form an , -unsaturated ketone (4-methylpent-3-en-2-one, also known as mesityl oxide). Reason (R) is incorrect: The dehydration of -hydroxy ketones is highly favorable upon heating because the resulting carbon-carbon double bond is conjugated with the carbonyl group, not isolated. This extended con

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