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NEETChemistryAldehydes and Ketones

Which of the following reagents reacts with acetone to yield a pure nucleophilic addition product without the subsequent elimination of a water molecule?

Options

  1. A2,4-Dinitrophenylhydrazine
  2. BHydroxylamine
  3. CHydrogen cyanide
  4. Dp -Toluidine

Correct answer

C. Hydrogen cyanide

Step-by-step solution

Acetone undergoes nucleophilic addition with hydrogen cyanide ( HCN ) to form a cyanohydrin. This is a pure nucleophilic addition reaction where no elimination of water takes place. Reagents like 2,4-dinitrophenylhydrazine, hydroxylamine, and primary amines (such as p -toluidine) are ammonia derivatives ( NH ₂- Z ). They react with carbonyl compounds via a nucleophilic addition-elimination mechanism, where the initial addition is followed by the elimination of a water molecule to form a carbon-nitrogen double bond

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