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NEETChemistryAldehydes and Ketones

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): Reduction of methyl 4-oxopentanoate with NaBH ₄ yields methyl 4-hydroxypentanoate. Reason (R): NaBH ₄ is a strong reducing agent that readily reduces ester groups to primary alcohols. In the light of the above statements, choose the most appropriate answer from the options given below:

Options

  1. ABoth Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of Assertion (A)
  2. BBoth Assertion (A) and Reason (R) are true but Reason (R) is not the correct explanation of Assertion (A)
  3. CAssertion (A) is true but Reason (R) is false
  4. DAssertion (A) is false but Reason (R) is true

Correct answer

C. Assertion (A) is true but Reason (R) is false

Step-by-step solution

Assertion (A) is true because NaBH ₄ is a chemoselective reducing agent that reduces ketones to secondary alcohols while leaving ester groups intact. Thus, the ketone group at C-4 in methyl 4-oxopentanoate is reduced to a secondary alcohol, forming methyl 4-hydroxypentanoate. Reason (R) is false because NaBH ₄ is a mild reducing agent and does not reduce esters, carboxylic acids, or amides. Stronger reducing agents like LiAlH ₄ are required to reduce esters to primary alcohols. Answer: Assertion (A) is true but Rea

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