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BITSAT 2017
Exam
BITSAT
Year
2017
Subject
Chemistry
Chapter
Chemical Kinetics

BITSAT 2017 · Chemistry · Chemical Kinetics

A graph is plotted between log K versus (1)/(T) for calculation of...

A graph is plotted between log KK versus 1T\dfrac{1}{T} for calculation of activation energy \left({E}_{a}\right)$. The correct plot is

A graph is plotted between log K versus (1)/(T) for calculation of activation energy ( E _ a ) . The correct plot isA graph is plotted between log K versus (1)/(T) for calculation of activation energy ( E _ a ) . The correct plot isA graph is plotted between log K versus (1)/(T) for calculation of activation energy ( E _ a ) . The correct plot isA graph is plotted between log K versus (1)/(T) for calculation of activation energy ( E _ a ) . The correct plot is

Options

  1. AA body at rest is moved along a horizontal straight line by a machine delivering a constant power. The distance moved
  2. BA body at rest is moved along a horizontal straight line by a machine delivering a constant power. The distance moved
  3. CA body at rest is moved along a horizontal straight line by a machine delivering a constant power. The distance moved
  4. DA body at rest is moved along a horizontal straight line by a machine delivering a constant power. The distance moved

Correct answer

B. A body at rest is moved along a horizontal straight line by a machine delivering a constant power. The distance moved

Step-by-step solution

According to Arrhenius equation,

k∝Tk ∝ T and k=Ae−Ea/RTk = {Ae}^{- Ea / RT}

logk=logA−Ea2.303×R×1Tlogk = logA - \dfrac{Ea}{2. 303 \times R} \times \dfrac{1}{T}

y=mx+cy = mx + c, the equation of straight line

The value of log kk should increase uniformily with TT or decrease with 1T\dfrac{1}{T}.

& & & & & & & & A graph is plotted between log K versus (1)/(T) for calculation of activation energy ( E _ a ) . The correct plot is

From this, that the slope is negative, which means that angle with x - axis is greater than 90° also that the point on which the straight line of graph intercepts the y - axis is log A which is positive.

Hence all the conclusions point out towards option b as it has negative slope and a positive y intercept.

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