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BITSAT 2016
Exam
BITSAT
Year
2016
Subject
Chemistry
Chapter
Chemical Kinetics

BITSAT 2016 · Chemistry · Chemical Kinetics

Consider the reaction : Cl_ 2 (a q)+H_ 2 ~S(a q) arrow S(s)+2 H^ +...

Consider the reaction : Cl2(aq)+H2 S(aq)→\mathrm{Cl}_{2}(a q)+\mathrm{H}_{2} \mathrm{~S}(a q) \rightarrow S(s)+2H+(aq)+2Cl−(aq)\mathrm{S}(s)+2 \mathrm{H}^{+}(a q)+2 \mathrm{Cl}^{-}(a q) The rate equation for this reaction is rate =k=k\left[\mathrm{Cl}_{2}\right][H2 S]\left[\mathrm{H}_{2} \mathrm{~S}\right] Which of these mechanisms is/are consistent with this rate equation? A. Cl2+H2 S→H++Cl−+Cl++HS−\mathrm{Cl}_{2}+\mathrm{H}_{2} \mathrm{~S} \rightarrow \mathrm{H}^{+}+\mathrm{Cl}^{-}+\mathrm{Cl}^{+}+\mathrm{HS}^{-} (slow) Cl++HS−→H++Cl−+S\mathrm{Cl}^{+}+\mathrm{HS}^{-} \rightarrow \mathrm{H}^{+}+\mathrm{Cl}^{-}+\mathrm{S} B. H2 S⇌H++HS−\mathrm{H}_{2} \mathrm{~S} \rightleftharpoons \mathrm{H}^{+}+\mathrm{HS}^{-} (fast equilibrium) Cl2+HS−→2Cl−+H++S\mathrm{Cl}_{2}+\mathrm{HS}^{-} \rightarrow 2 \mathrm{Cl}^{-}+\mathrm{H}^{+}+\mathrm{S} (Slow)

Options

  1. AB\mathrm{B} only
  2. B\quad Both A\mathrm{A} and B\mathrm{B}
  3. CNeither A nor B
  4. DA only

Correct answer

D. A only

Step-by-step solution

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