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BITSAT 2016
Exam
BITSAT
Year
2016
Subject
Chemistry
Chapter
Some Basic Concepts of Chemistry

BITSAT 2016 · Chemistry · Some Basic Concepts of Chemistry

1.25 g of a sample of Na_ 2 CO_ 3 and Na_ 2 SO_ 4 is dissolved in...

1.25g1.25 \mathrm{ g} of a sample of Na2CO3\mathrm{Na}_{2} \mathrm{CO}_{3} and Na2SO4\mathrm{Na}_{2} \mathrm{SO}_{4} is dissolved in 250ml250 \mathrm{ml} solution. 25ml25 \mathrm{ml} of this solution neutralises 20ml20 \mathrm{ml} of 0.1NH2SO40.1 \mathrm{ N} \mathrm{H}_{2} \mathrm{SO}_{4}. The %\% of Na2CO3\mathrm{Na}_{2} \mathrm{CO}_{3} in this sample is

Options

  1. A84.8%84.8 \%
  2. B8.48%8.48 \%
  3. C15.2%15.2 \%
  4. D42.4%42.4 \%

Correct answer

A. 84.8%84.8 \%

Step-by-step solution

Let the amount of Na2CO3\mathrm{Na}_{2} \mathrm{CO}_{3} present in the mixture be xg.Na2SO4\mathrm{xg}. \mathrm{Na}_{2} \mathrm{SO}_{4} will not react with H2SO4.\mathrm{H}_{2} \mathrm{SO}_{4}. Then x53=20×0.1×101000∴x=1.06g∴\frac{x}{53}=\frac{20 \times 0.1 \times 10}{1000} \therefore x=1.06 g\therefore Percentage of Na2CO3=1.06×1001.25=84.8%\mathrm{Na}_{2} \mathrm{CO}_{3}=\frac{1.06 \times 100}{1.25}=84.8 \%
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