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BITSAT 2018
Exam
BITSAT
Year
2018
Subject
Chemistry
Chapter
Thermodynamics (C)

BITSAT 2018 · Chemistry · Thermodynamics (C)

When the heat of a reaction at constant pressure is - 25 × 10 ^ - 3...

When the heat of a reaction at constant pressure is −25×10−3cal- 25 \times {10}^{- 3}cal and entropy change for the reaction is 7.4caldeg−17. 4cal{deg}^{- 1}, it is predicted that the reaction at 250C{25}^{0}C is

Options

  1. Arevesible
  2. Bspontaneous
  3. Cnon-spontaneous
  4. Dirreversible

Correct answer

B. spontaneous

Step-by-step solution

Heat at constant pressure means enthalpy. i.e., ΔG=ΔH−TΔS\Delta G = \Delta H - T \Delta S

ΔH=2.5×103cal\Delta H = 2. 5 \times {10}^{3}cal

ΔS=7.4caldeg−1\Delta S = 7. 4{caldeg}^{- 1}

T=298KT = 298K

ΔG=ΔH−TΔS\Delta G = \Delta H - T \Delta S

=−25×103−298×7.4= - 25 \times {10}^{3} - 298 \times 7. 4

=−4705.2cal= - 4705. 2cal

As the value of& ΔG& is& −4705.2& cal, which is a negative value, so this reaction will be spontaneous.&

Hence, the process is spontaneous.

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