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BITSAT Thermodynamics (C) PYQs with Solutions

34 previous year questions from Thermodynamics (C) (BITSAT Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

34 questionsChemistry2009–2024Answers + solutions

About Thermodynamics (C) PYQs

Thermodynamics (C) has 34 previous year questions in the Quantrex Academy BITSAT Chemistry bank. The 34 questions in this list come from BITSAT (34), spanning 2009 to 2024. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2024: 6
  • 2023: 2
  • 2022: 2
  • 2021: 1
  • 2020: 3
  • 2019: 1
  • 2018: 2
  • 2017: 2
  • 2016: 2
  • 2015: 2
  • 2014: 3
  • 2013: 2

Thermodynamics (C) questions with solutions

1

What would be the amount of heat absorbed in the cyclic process shown below?

BITSAT 2024 Solution
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2

The bond dissociation energy of X_2, Y_2 and X Y are in the ratio of 1: 0.5: 1. Δ H for the formation of X Y is -200 kJ / mol . The bond dissociation energy of X_2 will be

BITSAT 2024 Solution
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3

Which of the following relation is not correct?

BITSAT 2024 Solution
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4

The standard Gibbs energy (Δ G^0) for the following reaction is aligned & A(s)+B^ 2+ (aq) arrow A^ 2+ (aq)+B(s), K_ c =10^ 12 at & 25^ ∘ C aligned (K_c=. equilibrium constant )

BITSAT 2024 Solution
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5

The combustion of benzene (L) gives CO_2(~g) and H_2 O(L) . Given that heat of combustion of benzene at constant volume is -3263.9 ~kJ ~mol^ - ^1 at 25^ ^ ∘ C ; heat of combustion

BITSAT 2024 Solution
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6

Choose the correct option for free expansion of an ideal gas under adiabatic condition from the following:

BITSAT 2024 Solution
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7

Given that bond energies of H-H and Cl-Cl are 430 kJ mol^ -1 and 240 kJ mol^ -1 respectively and Δ H_ f for HCl is -90 kJ mol^ -1 , bond enthalpy of HCl is

BITSAT 2023 Solution
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8

If enthalpies of formation of C_2 H_4( g), CO_2( g) and H_2 O(l) at 25^ ^ ∘ C and 1 atm pressure are 52,394 and -286 kJ / mol respectively, the change in enthalpy for combustion

BITSAT 2023 Solution
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9

Standard entropy of X_2, Y_2 and X Y_2 are 60,40 and 50 JK^ -1 mol^ -1 , respectively. For the reaction, (1)/(2) X_2+(3)/(2) Y_2 X Y_3, Δ H=-30 kJ , to be at equilibrium, the

BITSAT 2022 Solution
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10

In an adiabatic process, no transfer of heat takes place between system and surrounding. Choose the correct option for free expansion of an ideal gas under adiabatic condition

BITSAT 2022 Solution
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11

Work out the heat change (cal) when 40 g of He gas at 27^ ^ ∘ C undergoes isothermal and reversible compression from initial pressure of 1 atm to 10 atm (R=2 cal K^ -1 mol^ -1 ).

BITSAT 2021 Solution
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12

For which one of the processes represented by the following equations the enthalpy (heat) change is likely to be negative

BITSAT 2020 Solution
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13

Acyclicprocess ABCD is shown in P-V diagram for an ideal gas. Which of the following diagram represents the same process?

BITSAT 2020 Solution
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14

For the combustion reaction at 298 K2 Ag(s)+1 / 2 O_ 2 ( g) 2 Ag_ 2 O(s) Which of the following alternatives is correct?

BITSAT 2020 Solution
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15

The heat of reaction for C _ 10 H _ 8 (s) + 12 O _ 2 (g) ⟶ 10 CO _ 2 (g) + 4 H _ 2 O ( l ) at constant volume is - 1228. 2kcal at 25 ^ 0 C . The heat of reaction at constant

BITSAT 2019 Solution
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16

Enthalpy of combustion of methane and ethane are - 210kcal / mol and - 368kcal / mol respectively. The enthalpy of combustion of decane is

BITSAT 2018 Solution
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17

When the heat of a reaction at constant pressure is - 25 × 10 ^ - 3 cal and entropy change for the reaction is 7. 4cal deg ^ - 1 , it is predicted that the reaction at 25 ^ 0 C is

BITSAT 2018 Solution
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18

Which of the following reactions does not involve absorption of energy? I. O(g) + e ^ - ⟶ O ^ - (g) II. S(g) + e ^ - ⟶ S ^ - (g) III. O ^ - (g) + e ^ - ⟶ O ^ 2 - (g) IV. Cl(g) + e

BITSAT 2017 Solution
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19

Which of the following show an increase in entropy? I. Boiling of water II. Melting of ice III. Freezing of water IV. Formation of hydrogen gas from water

BITSAT 2017 Solution
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20

For a particular reversible reaction at temperature T, Δ H and Δ S were found to be both +ve. If T_ e is the temperature at equilibrium, the reaction would be spontaneous when

BITSAT 2016 Solution
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21

Given F(g)+ ^ - arrow F^ - (g) (Electron gain enthalpy) Li^ + (g)+F^ - (g) arrow LiF(s) -1047Li(s)+(1)/(2) F_ 2 ( g) arrow LiF(s) -617 Based on data provided, the value of

BITSAT 2016 Solution
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22

Which law of the thermodynamics helps in calculating the absolute entropies of various substances at different temperatures?

BITSAT 2015 Solution
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23

A spontaneous reaction is impossible if

BITSAT 2015 Solution
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24

The enthalpy of sublimation of aluminium is 330 kJ / mol . Its Ist, II ^ nd and III ^ rd ionization enthalpies are 580,1820 and 2740 ~kJ respectively. How much heat has too be

BITSAT 2014 Solution
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25

If the enthalpy of vaporization of water is 186.5 kJmol^ -1 , the entropy if its vaporization will be:

BITSAT 2014 Solution
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26

The heats of neutralisation of CH_ 3 COOH , HCOOH, HCN and H_ 2 S are -13.2,-13.4,-2.9 and -3.8 kCal per equivalent respectively. Arrange the acids in increasing order of acidic

BITSAT 2014 Solution
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27

For the dissociation reaction, H_ 2 ( g) arrow 2 H(g) Δ H=162 Kcal heat of atomisation of H is

BITSAT 2013 Solution
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28

The enthalpy of combustion of 2 moles of benzene at 27^ ^ ∘ C differs from the value determined in bomb calorimeter by

BITSAT 2013 Solution
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29

In which of the following reactions, standard entropy change (Δ S^ ∘ ) is positive and standard Gibb's energy change (Δ G^ ∘ ) decreases sharply with increasing temperature?

BITSAT 2012 Solution
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30

What is the free energy change, Δ G , when 1.0 mole of water at 100^ ^ ∘ C and 1 atm pressure is converted into steam at 100^ ^ ∘ C and 1 atm . pressure?

BITSAT 2011 Solution
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31

At a constant volume the specific heat of a gas is 0.075 and its molecular weight is 40. The gas is:

BITSAT 2010 Solution
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32

Which one of the following is correct regarding Δ H:

BITSAT 2009 Solution
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33

One mole of an ideal gas at 300 ~K is expanded isothermally from an initial volume of 1 litre to 10 litres. The Δ E for this process is (R=2. cal .mol^ -1 ~K^ -1 )

BITSAT 2009 Solution
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34

At 25^ ^ ∘ C and 1 bar which of the following has a non-zero Δ H_ ^ ^ ∘ ?

BITSAT 2009 Solution
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