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BITSAT2016ChemistryThermodynamics (C)Actual

Given F ( g )+ e ⁻ F ⁻( g ) (Electron gain enthalpy) Li ⁺( g )+ F ⁻( g ) LiF ( s ) -1047 Li ( s )+ 1 2 ~F ₂( ~g ) LiF ( s ) -617 Based on data provided, the value of electron gain enthalpy of fluorine would be:

Options

  1. A-300 ~kJ ~mol ⁻¹
  2. B-350 ~kJ ~mol ⁻¹
  3. C-328 ~kJ ~mol ⁻¹
  4. D-228 ~kJ ~mol ⁻¹

Correct answer

C. -328 ~kJ ~mol ⁻¹

Step-by-step solution

Applying Hess's Law array c _ f H ^ = _ sub H + 1 2 _ diss H + L .E. + E . A + _ lattice H -617=161+520+77+ E A .+(-1047) E . A .=-617+289=-328 ~kJ ~mol ⁻¹ array electron affinity of fluorine =-328 ~kJ ~mol ⁻¹

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