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BITSAT 2015
Exam
BITSAT
Year
2015
Subject
Chemistry
Chapter
Thermodynamics (C)

BITSAT 2015 · Chemistry · Thermodynamics (C)

Which law of the thermodynamics helps in calculating the absolute...

Which law of the thermodynamics helps in calculating the absolute entropies of various substances at different temperatures?

Options

  1. AFirst law
  2. BSecond law
  3. CThird law
  4. DZeroth law

Correct answer

C. Third law

Step-by-step solution

The third law helps to calculate the absolute entropies of pure substances at different temperature. The entropy of the substance at different temperature. T\mathrm{T} may be calculated by the measurement of heat capacity change ST−S0=ΔS=∫0TCpdtT Where ST= Entropy at TK\begin{array}{l}\mathrm{S}_{\mathrm{T}}-\mathrm{S}_{0}=\Delta \mathrm{S}=\int_{0}^{\mathrm{T}} \frac{\mathrm{C}_{\mathrm{p}} \mathrm{dt}}{\mathrm{T}}\\ \text{ Where } \mathrm{S}_{\mathrm{T}}=\text{ Entropy at } \mathrm{T} \mathrm{K} \end{array}\mathrm{S}_{0}=EntropyatEntropy at0 \mathrm{ K} =Cp⋅log⁡eT=2.303Cplog⁡T\begin{array}{l} =\mathrm{C}_{\mathrm{p}} \cdot \log _{e} \mathrm{ T}\\ =2.303 \mathrm{C}_{\mathrm{p}} \mathrm\log \mathrm{T} \end{array}$
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