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JEE Advanced 2023Paper 2
Exam
JEE Advanced
Year
2023
Paper
Paper 2
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Advanced 2023 · Paper 2 · Chemistry · Chemical Bonding and Molecular Structure

Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 ,...

Among [I3]+,[SiO4]4−,SO2Cl2,XeF2,SF4,ClF3,Ni(CO)4,XeO2F2,[PtCl4]2−,XeF4{\left[{I}_{3}\right]}^{+}, {\left[{SiO}_{4}\right]}^{4 -}, {SO}_{2}{Cl}_{2}, {XeF}_{2}, {SF}_{4}, {ClF}_{3}, Ni{\left(CO\right)}_{4}, {XeO}_{2}{F}_{2}, {\left[{PtCl}_{4}\right]}^{2 -}, {XeF}_{4}, and SOCl2{SOCl}_{2}, the total number of species having sp3{sp}^{3} hybridised central atom isAmong [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [

Correct answer

5

Step-by-step solution

I3+{I}^{3 +} ion has sp3{sp}^{3} hybridisation and bent shape containing two bond pairs and two lone pairs. Structure of SiO44−{{SiO}_{4}}^{4 -} is tetrahedral structure and SiSi is sp3{sp}^{3} hybridised. The molecular geometry of SOCl2{SOCl}_{2} is trigonal pyramidal and its electron geometry is tetrahedral. In this molecule sulphur undergo sp3{sp}^{3} hbridisation,

Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [

Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [

XeF2{XeF}_{2} molecule is linear molecule but it is sp3d{sp}^{3}d hybridised. In SF4{SF}_{4}, sulphur undergo sp3d{sp}^{3}d hybridisation and molecule has see-saw shape. In ClF3{ClF}_{3}, chlorine undergo sp3d{sp}^{3}d hybridisation and shape of the molecule is T-shape.

Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [

Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [

The nickel tetracarbonyl is a tetrahedral complex in which nickel metal undergo sp3{sp}^{3} hybridisation. In the molecule XeO2F2{XeO}_{2}{F}_{2}, XeXe undergo sp3d{sp}^{3}d hybridisation and molecular shape is see-saw. Tetrachloroplatinate(II) is a square planar complex in which platinum undergoes dsp2{dsp}^{2} hbridisation.

Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [

XeF4{XeF}_{4} is square planar compound in which xenon undergoes sp3d2{sp}^{3}{d}^{2} hybridisation. In the tetrahedral molecule SO2Cl2{SO}_{2}{Cl}_{2}, sulphur undergoes sp3{sp}^{3} hybridisation.

Among [ I _ 3 ] ^ + , [ SiO _ 4 ] ^ 4 - , SO _ 2 Cl _ 2 , XeF _ 2 , SF _ 4 , ClF _ 3 , Ni (CO) _ 4 , XeO _ 2 F _ 2 , [

Hence, the total number of sp3{sp}^{3} hybridised central atom molecules are 5.

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