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JEE Main 20266 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
6 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2026 · 6 April · Morning Shift · Chemistry · Chemical Bonding and Molecular Structure

The pairs among A = [SO_3^ 2- , CO_3^ 2- ] , B = [O_2^ 2- , F_2] ,...

The pairs among A=[SO32−,CO32−]A = [\text{SO}_3^{2-}, \text{CO}_3^{2-}], B=[O22−,F2]B = [\text{O}_2^{2-}, \text{F}_2], C=[CN−,CO]C = [\text{CN}^-, \text{CO}], D=[NH3,H3O+]D = [\text{NH}_3, \text{H}_3\text{O}^+] and E=[MnO42−,CrO42−]E = [\text{MnO}_4^{2-}, \text{CrO}_4^{2-}] that do not have similar Lewis dot structure are

Options

  1. AA, B and E
  2. BA and E
  3. CB, C and D
  4. DC and D

Correct answer

B. A and E

Step-by-step solution

Species with the same number of valence electrons and the same skeletal structure generally have similar Lewis dot structures (isoelectronic species).

For pair A: SO32−\text{SO}_3^{2-} has 6+3(6)+2=266 + 3(6) + 2 = 26 valence electrons. CO32−\text{CO}_3^{2-} has 4+3(6)+2=244 + 3(6) + 2 = 24 valence electrons. Since they have different numbers of valence electrons, they do not have similar Lewis dot structures (SO32−\text{SO}_3^{2-} has a lone pair on the central atom and is pyramidal, while CO32−\text{CO}_3^{2-} has no lone pair on the central atom and is trigonal planar).

For pair B: O22−\text{O}_2^{2-} has 2(6)+2=142(6) + 2 = 14 valence electrons. F2\text{F}_2 has 2(7)=142(7) = 14 valence electrons. Both have a single bond and three lone pairs on each atom, so they have similar Lewis dot structures.

For pair C: CN−\text{CN}^- has 4+5+1=104 + 5 + 1 = 10 valence electrons. CO\text{CO} has 4+6=104 + 6 = 10 valence electrons. Both have a triple bond and one lone pair on each atom, so they have similar Lewis dot structures.

For pair D: NH3\text{NH}_3 has 5+3(1)=85 + 3(1) = 8 valence electrons. H3O+\text{H}_3\text{O}^+ has 6+3(1)−1=86 + 3(1) - 1 = 8 valence electrons. Both have three single bonds and one lone pair on the central atom, so they have similar Lewis dot structures.

For pair E: MnO42−\text{MnO}_4^{2-} has 7+4(6)+2=337 + 4(6) + 2 = 33 valence electrons. CrO42−\text{CrO}_4^{2-} has 6+4(6)+2=326 + 4(6) + 2 = 32 valence electrons. Since they have different numbers of valence electrons (MnO42−\text{MnO}_4^{2-} has an unpaired electron), they do not have similar Lewis dot structures.

Thus, pairs A and E do not have similar Lewis dot structures.

Answer: A and E
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