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JEE Main 20266 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
6 April
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2026 · 6 April · Evening Shift · Chemistry · Chemical Bonding and Molecular Structure

Given below are two statements : Statement I : F _2 O Statement II...

Given below are two statements :
Statement I : F2_2O << H2_2O << Cl2_2O is the correct trend in terms of bond angle.
Statement II : SiF4_4, SnF4_4 and PbF4_4 are ionic in nature.
In the light of the above statements, choose the correct answer from the options given below :

Options

  1. ABoth Statement I and Statement II are true
  2. BBoth Statement I and Statement II are false
  3. CStatement I is true but Statement II is false
  4. DStatement I is false but Statement II is true

Correct answer

C. Statement I is true but Statement II is false

Step-by-step solution

In Statement I, the bond angle of F2OF_2O is 103∘103^{\circ}, H2OH_2O is 104.5∘104.5^{\circ}, and Cl2OCl_2O is 110.9∘110.9^{\circ}. The increasing order of bond angle is F2O<H2O<Cl2OF_2O < H_2O < Cl_2O. In F2OF_2O, the high electronegativity of fluorine shifts the bond pairs towards fluorine, decreasing bond pair-bond pair repulsion and thus decreasing the bond angle. In Cl2OCl_2O, steric hindrance between the large chlorine atoms increases the bond angle. Thus, Statement I is true.

In Statement II, SiF4SiF_4 is a covalent compound (it is a gas at room temperature), whereas SnF4SnF_4 and PbF4PbF_4 are ionic solids. Thus, Statement II is false.

Answer: Statement I is true but Statement II is false
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