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JEE Advanced 2017Paper 1
Exam
JEE Advanced
Year
2017
Paper
Paper 1
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Advanced 2017 · Paper 1 · Chemistry · Chemical Bonding and Molecular Structure

The sum of the number of lone pairs of electrons on each central...

The sum of the number of lone pairs of electrons on each central atom in the following species is[TeBr6]2−,[BrF2]+,SNF3and[XeF3]−is{\left[TeB{r}_{6}\right]}^{2 -}, {\left[Br{F}_{2}\right]}^{+}, SN{F}_{3}and{\left[Xe{F}_{3}\right]}^{-} [Atomic number : N=7,F=9,S=16,Br=35,Te=52,Xe=54]N = 7, F = 9, S = 16, Br = 35, Te = 52, Xe = 54 ]

Correct answer

6

Step-by-step solution

Number of σ\sigma-bonds formed by central metal atom/ ion Number of lone pairs on central metal atom/ ion
(i) In[TeBr6]2−{In \left[TeB{r}_{6}\right]}^{2 -} 6 1
(ii) In[BrF2]+In {\left[Br{F}_{2}\right]}^{+} 2 2
(iii) InSNF3In SN{F}_{3} 4 0
(iv) In[XeF3]−In {\left[Xe{F}_{3}\right]}^{-} 3 3

⇒⇒ Total number of lone pairs of electrons =1+2+0+3= 1 + 2 + 0 + 3

=6= 6

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