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JEE Advanced 2014Paper 1
Exam
JEE Advanced
Year
2014
Paper
Paper 1
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Advanced 2014 · Paper 1 · Chemistry · Chemical Bonding and Molecular Structure

Hydrogen bonding plays a central role in the following phenomena:

Hydrogen bonding plays a central role in the following phenomena:Hydrogen bonding plays a central role in the following phenomena:Hydrogen bonding plays a central role in the following phenomena:

Options

  1. AIce floats in water
  2. BHigher Lewis basicity of primary amines than tertiary amines in aqueous solutions Higher Lewis basicity of primary amines than tertiary amines in aqueous solutions
  3. CFormic acid is more acidic than acetic acid
  4. DDimerisation of acetic acid in benzene

Correct answer

A. Ice floats in water

Step-by-step solution

A] Ice has cage-like structure in which each water molecule is surrounded by four other water molecules tetrahedral through hydrogen boding, due to this density of ice is less than water and it floats in water.
B]

Hydrogen bonding plays a central role in the following phenomena:
The cation (I) more stabilized through hydrogen boding than cation II . So, R−NH2R - N{H}_{2} is better base than (R){\left(R\right)}_{3}Ninaqueoussolution.<br>C]HCOOHisstrongeracidthanin aqueous solution.<br >C] HCOOH is stronger acid thanC{H}_{3}COOH due to inductive effect and not due to hydrogen bonding.
D] Acetic acid dimerizes in benzene through intermolecular hydrogen bonding.

Hydrogen bonding plays a central role in the following phenomena:

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