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JEE Advanced 2006
Exam
JEE Advanced
Year
2006
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Advanced 2006 · Chemistry · Chemical Bonding and Molecular Structure

If the bond length of CO bond in carbon monoxide is 1.128 ~A^ ,...

If the bond length of CO\mathrm{CO} bond in carbon monoxide is 1.128 A∘1.128 \mathrm{~A}^{\circ}, then what is the value of CO\mathrm{CO} bond length in Fe(CO)5\mathrm{Fe}(\mathrm{CO})_5 ?

Options

  1. A1.15A˚1.15 Å
  2. B1.128A˚1.128 Å
  3. C1.72A˚1.72 Å
  4. D1.118A˚1.118 Å

Correct answer

A. 1.15A˚1.15 Å

Step-by-step solution

The metal (Fe) makes the back bonding to CO\mathrm{CO}. The metal to ligand bonding creates a synergic effect which strengthens the bond CO\mathrm{CO} and the metal ( Fe\mathrm{Fe} ). Which results in the contraction of CO\mathrm{CO} bond length (Synergic means working together towards a common end. This is a bond formed by a ligand to metal ion which has a σ\sigma-bond from ligand to metal ion and the back donation of electron density from the metal to the π∗\pi^* orbitals on the ligand. Thus enhancing the acceptor strength of the p-orbital. Hence up to a point the effect of σ\sigma-bond formation strengthens the π\pi-bonding or vice-versa. Due to this synergic effect bond order decreases.
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