JEE Advanced 2006
- Exam
- JEE Advanced
- Year
- 2006
- Subject
- Chemistry
- Chapter
- Chemical Bonding and Molecular Structure
JEE Advanced 2006 · Chemistry · Chemical Bonding and Molecular Structure
If the bond length of CO bond in carbon monoxide is 1.128 ~A^ ,...
If the bond length of bond in carbon monoxide is , then what is the value of bond length in ?
Options
- A
- B
- C
- D
Correct answer
A.
Step-by-step solution
The metal (Fe) makes the back bonding to . The metal to ligand bonding creates a synergic effect which strengthens the bond and the metal ( ). Which results in the contraction of bond length (Synergic means working together towards a common end. This is a bond formed by a ligand to metal ion which has a -bond from ligand to metal ion and the back donation of electron density from the metal to the orbitals on the ligand. Thus enhancing the acceptor strength of the p-orbital. Hence up to a point the effect of -bond formation strengthens the -bonding or vice-versa. Due to this synergic effect bond order decreases.