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JEE Advanced 2020Paper 1
Exam
JEE Advanced
Year
2020
Paper
Paper 1
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Advanced 2020 · Paper 1 · Chemistry · General Organic Chemistry

With respect to the compounds I - V choose the correct statement(s).

With respect to the compounds I−VI - V choose the correct statement(s).

With respect to the compounds I - V choose the correct statement(s).

Options

  1. AThe acidity of compound II is due to delocalization in the conjugate base.
  2. BThe conjugate base of compound IVIV is aromatic.
  3. CCompound IIII becomes more acidic, when it has a−NO2- {NO}_{2} substituent.
  4. DThe acidity of compounds follows the order I>IV>V>II>IIII > IV > V > II > III.

Correct answer

A. The acidity of compound II is due to delocalization in the conjugate base.

Step-by-step solution

(A)( A )

With respect to the compounds I - V choose the correct statement(s). 

is stabilised by conjugation

(B)( B ) Conjugation base of With respect to the compounds I - V choose the correct statement(s). is With respect to the compounds I - V choose the correct statement(s). which is an aromatic anion

(C)( C ) −NO2- {NO}_{2}  group is an electron withdrawing group it increases acidic strength of any compound to which
it is added.

(D)( D ) The acidic strength order on the basis of pKa{pK}_{a} data IV>V>I>II>IIIIV > V > I > II > III is 

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