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JEE Main 20268 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
8 April
Shift
Evening Shift
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Main 2026 · 8 April · Evening Shift · Chemistry · General Organic Chemistry

The total number of aromatic compounds/species from the following is

The total number of aromatic compounds/species from the following is
The total number of aromatic compounds/species from the following is

Options

  1. A66
  2. B44
  3. C33
  4. D55

Correct answer

B. 44

Step-by-step solution

A species is aromatic if it is cyclic, planar, fully conjugated (continuous cyclic overlap of pp-orbitals) and contains (4n+2) π(4n + 2)\,\pi electrons (Huckel's rule). Let us analyse each species.

1,41,4-Benzoquinone:
The six-membered ring has only 4π4\pi electrons (from the two C=CC=C bonds); the two C=OC=O groups are cross-conjugated and do not contribute to a continuous (4n+2) π(4n + 2)\,\pi ring system. Hence, it is non-aromatic.

Tropylium cation:
A planar, cyclic, fully conjugated seven-membered system with three C=CC=C bonds and a positive charge (empty pp-orbital). It has 6 π6\,\pi electrons, satisfying Huckel's rule with n=1n = 1. It is aromatic.

Phenanthrene:
A fused tricyclic, planar, fully conjugated hydrocarbon with 14 π14\,\pi electrons. It obeys Huckel's rule with n=3n = 3. It is aromatic.

1,21,2-Dihydronaphthalene:
It contains an intact benzene ring fused to a partially saturated six-membered ring. Because of the benzene ring, the molecule as a whole is classified as aromatic.

Cyclobutadiene dication:
A planar, four-membered ring with one C=CC=C bond and two positive charges (two empty pp-orbitals), giving 2 π2\,\pi electrons. It satisfies Huckel's rule with n=0n = 0. It is aromatic.

Cyclohexadienyl anion (as drawn with a −CH2−-CH_2- group):
The sp3sp^3 −CH2−-CH_2- carbon breaks the continuous cyclic conjugation, so the ring is not fully conjugated. Hence, it is non-aromatic.

Counting the aromatic species: tropylium cation, phenanthrene, 1,21,2-dihydronaphthalene and cyclobutadiene dication give a total of 44 aromatic species.

Hence, the correct option is (2) 4(2)\ 4.
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