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JEE Main 20266 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
6 April
Shift
Evening Shift
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Main 2026 · 6 April · Evening Shift · Chemistry · General Organic Chemistry

Shown below is the structure of methyl acetate with three different...

Shown below is the structure of methyl acetate with three different α\alpha, β\beta and γ\gamma carbon - oxygen bonds.
Shown below is the structure of methyl acetate with three different α , β and γ carbon - oxygen bonds. The correct
The correct order of bond lengths of these bonds is :

Options

  1. Aα>β>γ\alpha > \beta > \gamma
  2. Bα<β<γ\alpha < \beta < \gamma
  3. Cα=β=γ\alpha = \beta = \gamma
  4. Dα<β=γ\alpha < \beta = \gamma

Correct answer

B. α<β<γ\alpha < \beta < \gamma

Step-by-step solution

In methyl acetate, the α\alpha bond is a C=OC=O double bond, which is the shortest among the three.

The β\beta bond is a C−OC-O single bond adjacent to a carbonyl group. Due to resonance (CH3−C(=O)−O−CH3↔CH3−C(−O−)=O+−CH3CH_3-C(=O)-O-CH_3 \leftrightarrow CH_3-C(-O^-)=O^+-CH_3), the β\beta bond acquires partial double bond character, making it shorter than a pure single bond.

The γ\gamma bond is a pure C−OC-O single bond between an sp3sp^3 hybridized carbon and oxygen, with no resonance involvement. Thus, it is the longest bond.

Therefore, the correct order of bond lengths is α<β<γ\alpha < \beta < \gamma.

Answer: α<β<γ\alpha < \beta < \gamma
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