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JEE Advanced 2017Paper 1
Exam
JEE Advanced
Year
2017
Paper
Paper 1
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Advanced 2017 · Paper 1 · Chemistry · General Organic Chemistry

The correct statement(s) for the following addition reactions...

The correct statement(s) for the following addition reactions is(are)
The correct statement(s) for the following addition reactions is(are)

Options

  1. AO and P are identical molecules
  2. B(M and O) and (N and P) are two pairs of enantiomers
  3. C(M and O) and (N and P) are two pairs of diastereomers
  4. DBromination proceeds through trans-addition in both the reactions

Correct answer

C. (M and O) and (N and P) are two pairs of diastereomers

Step-by-step solution

The correct statement(s) for the following addition reactions is(are)

(M) and (N) are identical meso compounds

The correct statement(s) for the following addition reactions is(are)

(O) and (P) are enantiomers

Explanation of 4 options :

(i) (M) and (O) are distereomers of each other.

(N) and (P) are distereomers of each other.

(ii) Addition of Br2B{r}_{2} on alkene follows non-classical carbocation mechanism. It is anti or trans addition.

(iii) (O) and (P) are enantiomers

(iv) (M) and (N) are identical and (O) and (P) are enantiomers.

(M and O) are distereomers and (N and P) are distereomers.

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