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JEE Advanced 2009Paper 2
Exam
JEE Advanced
Year
2009
Paper
Paper 2
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Advanced 2009 · Paper 2 · Chemistry · General Organic Chemistry

In the following carbocation, H / CH_3 that is most likely to...

In the following carbocation, H/CH3\mathrm{H} / \mathrm{CH}_3 that is most likely to migrate to the positively charged carbon is In the following carbocation, H / CH_3 that is most likely to migrate to the positively charged carbon is

Options

  1. ACH3\mathrm{CH}_3 at C−4\mathrm{C}-4
  2. BH\mathrm{H} at C−4\mathrm{C}-4
  3. CCH3\mathrm{CH}_3 at C−2\mathrm{C}-2
  4. DH\mathrm{H} at C−2\mathrm{C}-2

Correct answer

D. H\mathrm{H} at C−2\mathrm{C}-2

Step-by-step solution

Hydride shift from C−2\mathrm{C}-2 will give most stable resonance stabilised carbocation as Fig.
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