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JEE Advanced 2008Paper 1
Exam
JEE Advanced
Year
2008
Paper
Paper 1
Subject
Chemistry
Chapter
General Organic Chemistry

JEE Advanced 2008 · Paper 1 · Chemistry · General Organic Chemistry

The correct statement(s) about the compound given below is are

The correct statement(s) about the compound given below is are The correct statement(s) about the compound given below is are

Options

  1. Athe compound is optically active
  2. Bthe compound possesses centre of symmetry
  3. Cthe compound possesses plane of symmetry
  4. Dthe compound possesses axis of symmetry

Correct answer

A. the compound is optically active

Step-by-step solution

The correct statement(s) about the compound given below is are
The compound does not possess centre of symmetry and plane of symmetry but possesses the proper axis of symmetry (Cn)\left(C_n\right). A CnC_n axis of symmetry is an axis about which the molecule can be rotated by 360∘/n360^{\circ} / n and thereby produce a molecule indistinguishable from the original molecule.The correct statement(s) about the compound given below is are
From this face H\mathrm{H}(on )andCland \mathrm{Cl} (on left) are facing towards us and again on rotating at 180∘C−2180^{\circ} \mathrm{C}-2 comes at C−1\mathrm{C}-1 place and again H\mathrm{H}(on )andCland \mathrm{Cl} (on left) are facing. We get an indistinguishable form on 180∘180^{\circ} rotation, so it has a proper axis of symmetry \left(C_2\right).Ifamoleculeisnotsuperimposableonitsmirrorimage,thatmoleculecanexhibitopticalactivity,ifthesehaveproperaxisbutnoimproperaxisorifa. If a molecule is not superimposable on its mirror image, that molecule can exhibit optical activity, if these have proper axis but no improper axis or if aC_n axis be the only symmetry element present in a molecule, that molecule is optically active.
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