JEE Advanced2017ChemistryHydrogenActual
Which of the following combinations will produce H 2 gas?
Options
- AZn metal and N a O H a q
- BAu metal and N a C N a q in the presence of air
- CCu metal and conc. H N O 3
- DFe metal and conc. H N O 3
Correct answer
A. Zn metal and N a O H a q
Step-by-step solution
(i) Z n + 2 N a O H → N a 2 Z n O 2 + H 2 (ii) 4 A u + 8 N a C N + O 2 + 2 H 2 O → 4 N a A u C N 2 + 4 N a O H (iii) C u + 4 H N O 3 → C u N O 3 2 + 2 N O 2 + 2 H 2 O conc. (iv) Formation of passive layer of F e 2 O 3 on the surface of Fe and N O 2 gas is evolved. F e + 4 H N O 3 → F e ( N O 3 ) 3 + N O 2 + 1 2 O 2