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JEE Advanced 2011Paper 1
Exam
JEE Advanced
Year
2011
Paper
Paper 1
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Advanced 2011 · Paper 1 · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Extra pure N_2 can be obtained by heating

Extra pure N2\mathrm{N}_2 can be obtained by heating

Options

  1. ANH3\mathrm{NH}_3 with CuO\mathrm{CuO}
  2. BNH4NO4\mathrm{NH}_4 \mathrm{NO}_4
  3. C(NH4)2Cr2O7\left(\mathrm{NH}_4\right)_2 \mathrm{Cr}_2 \mathrm{O}_7
  4. DBa(N3)2\mathrm{Ba}\left(\mathrm{N}_3\right)_2

Correct answer

D. Ba(N3)2\mathrm{Ba}\left(\mathrm{N}_3\right)_2

Step-by-step solution

Ba(N3)2⟶ Heat Ba(s)+3N2(g)\mathrm{Ba}\left(\mathrm{N}_3\right)_2 \stackrel{\text{ Heat }}{\longrightarrow} \mathrm{Ba}(\mathrm{s})+3 \mathrm{ N}_2(\mathrm{ g}) Azide salt of barium can be obtained in purest form as well as the decomposition product contain solid Ba\mathrm{Ba} as byproduct along with gaseous nitrogen, hence no additional step of separation is required. Other reactions are:
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