JEE Advanced2026ChemistryStates of MatterActual
Two cylinders, both fitted with frictionless pistons, are filled with mixtures of He and Ar gases. In the first cylinder, the masses of He and Ar are m₁ and m₂ , respectively. In the second cylinder, the masses of He and Ar are m₂ and m₁ , respectively. The molar mass of Ar is 10 times the molar mass of He. The external pressure applied by the piston on the first cylinder needs to be 5 times that on the second cylind
Correct answer
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Step-by-step solution
Let the molar mass of He be M . Then the molar mass of Ar is 10M . In the first cylinder, the total number of moles is given by: n₁ = m₁ M + m₂ 10M = 10m₁ + m₂ 10M In the second cylinder, the total number of moles is given by: n₂ = m₂ M + m₁ 10M = 10m₂ + m₁ 10M Using the ideal gas equation PV = nRT , since the volume and temperature are the same for both cylinders, the pressure is directly proportional to the number of moles. Thus, P₁ P₂ = n₁ n₂ . Given that P₁ = 5P₂ , we have: n₁ n₂ = 5 Substituting the expression