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JEE Advanced 2023Paper 1
Exam
JEE Advanced
Year
2023
Paper
Paper 1
Subject
Chemistry
Chapter
States of Matter

JEE Advanced 2023 · Paper 1 · Chemistry · States of Matter

A gas has a compressibility factor of 0 . 5 and a molar volume of 0...

A gas has a compressibility factor of 0.50 . 5 and a molar volume of 0.4dm3mol−10 . 4{dm}^{3}{mol}^{- 1} at a temperature of 800K800K and pressure xatmxatm. If it shows ideal gas behaviour at the same temperature and pressure, the molar volume will be ydm3mol−1y{dm}^{3}{mol}^{- 1} . The value ofx/yx / y is _________

[Use: Gas constant, R=8×10−2LatmK−1mol−1R = 8 \times {10}^{- 2}Latm{K}^{- 1}{mol}^{- 1} ]

Correct answer

0

Step-by-step solution

Compressibility factor (Z)=VrealVideal=0.5( Z )= \dfrac{{V}_{real}}{{V}_{ideal}} = 0 . 5

Vreal=0.4dm3mol−1=0.4L/mol{V}_{real} = 0 . 4{dm}^{3}{mol}^{- 1} = 0 . 4L / mol

∴Videal=0.40.5=0.8L/mol∴ {V}_{ideal} = \dfrac{0 . 4}{0 . 5} = 0 . 8L / mol

∴y=0.8L/mol∴ y = 0 . 8L / mol

Using ideal gas equation : PV=nRTPV = nRT

P=1×8×10−2×8000.8P = \dfrac{1 \times 8 \times {10}^{- 2} \times 800}{0 . 8}

x=80atmx = 80atm

∴xy=800.8=100∴ \dfrac{x}{y} = \dfrac{80}{0 . 8} = 100

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