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JEE Advanced 2017Paper 1
Exam
JEE Advanced
Year
2017
Paper
Paper 1
Subject
Chemistry
Chapter
States of Matter

JEE Advanced 2017 · Paper 1 · Chemistry · States of Matter

An ideal gas is expanded from ( p _ 1 , V _ 1 , T _ 1 ) to ( p _ 2...

An ideal gas is expanded from (p1,V1,T1)to(p2,V2,T2)( {p}_{1}, {V}_{1}, {T}_{1} ) to ( {p}_{2}, {V}_{2}, {T}_{2} ) under different conditions. The correct statement(s) among the following is(are)An ideal gas is expanded from ( p _ 1 , V _ 1 , T _ 1 ) to ( p _ 2 , V _ 2 , T _ 2 ) under different conditions. TheAn ideal gas is expanded from ( p _ 1 , V _ 1 , T _ 1 ) to ( p _ 2 , V _ 2 , T _ 2 ) under different conditions. The

Options

  1. AThe work done on the gas is maximum when it is compressed irreversibly from ( p2,V2){p}_{2}, {V}_{2} ) to (p1,V1)( {p}_{1}, {V}_{1} ) against constant pressure p1{p}_{1}
  2. BIf the expansion is carried out freely, it is simultaneously both isothermal as well as adiabatic
  3. CThe work done on the gas is less when it is expanded reversibly from V1toV2{V}_{1}to{V}_{2} under adiabatic conditions as compared to that when expanded reversibly from V1toV2{V}_{1}to{V}_{2} under isothermal conditions.
  4. DThe change in internal energy of the gas (i) zero, if it is expanded reversibly with T1=T2{T}_{1} = {T}_{2} , and (ii) positive, if it is expanded reversibly under adiabatic conditions with T1≠T2{T}_{1} \ne {T}_{2}

Correct answer

A. The work done on the gas is maximum when it is compressed irreversibly from ( p2,V2){p}_{2}, {V}_{2} ) to (p1,V1)( {p}_{1}, {V}_{1} ) against constant pressure p1{p}_{1}

Step-by-step solution

(I)

 An ideal gas is expanded from ( p _ 1 , V _ 1 , T _ 1 ) to ( p _ 2 , V _ 2 , T _ 2 ) under different conditions. The

(II) 

An ideal gas is expanded from ( p _ 1 , V _ 1 , T _ 1 ) to ( p _ 2 , V _ 2 , T _ 2 ) under different conditions. The

(III)  (i) \DeltaU=nCv\DeltaT=0\DeltaU = n{C}_{v}\DeltaT = 0 (isothermal hence \DeltaT=0\DeltaT = 0)

(ii)   \DeltaU=q+w=−ve(q=0,w<0)\DeltaU = q + w = - ve\left(q = 0, w < 0\right)

(IV)   q=0q = 0 (adiabatic), w=0w = 0 (free expansion)

\DeltaU=0⇒\DeltaT=0\DeltaU = 0 ⇒ \DeltaT = 0 (isothermal)

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