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JEE Advanced 2023Paper 1
Exam
JEE Advanced
Year
2023
Paper
Paper 1
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Advanced 2023 · Paper 1 · Chemistry · Thermodynamics (C)

One mole of an ideal monoatomic gas undergoes two reversible...

One mole of an ideal monoatomic gas undergoes two reversible processes (A→B( A \to B and B→C)B \to C ) as shown in the given figure:

One mole of an ideal monoatomic gas undergoes two reversible processes ( A → B and B → C ) as shown in the given

A→BA \to B is an adiabatic process. If the total heat absorbed in the entire process (A→B( A \to B and B→C)B \to C ) is RT2ln⁡10{RT}_{2}\ln 10, the value of 2log⁡V32{\log V}_{3} is
[Use molar heat capacity of the gas at constant pressure, Cp,m=52R{C}_{p, m} = \dfrac{5}{2}R]

Correct answer

0

Step-by-step solution

qA→C=RT2ln⁡10{q}_{A \to C} = {RT}_{2}\ln 10

qA→B=0{q}_{A \to B} = 0 (∵adiabatic)\text{(} ∵ \text{adiabatic)}

qA→C=qA→B+qB→C{q}_{A \to C} = {q}_{A \to B} + {q}_{B \to C}

qA→C=qB→C{q}_{A \to C} = {q}_{B \to C}

qA→c=nRT2ln{q}_{A \to c} = {nRT}_{2}ln\left(\dfrac{{V}_{3}}{{V}_{2}}\right)...(i)</p><p>For...(i)</p><p>ForB \to C<br/><br />\Delta E = q + w</p><p></p><p>\Delta E = 0(sinceisothermic)</p><p>(since isothermic)</p><p>q = - w</p><p></p><p>= - \left(- {nRT}_{2}ln\dfrac{{V}_{3}}{{V}_{2}}\right)</p><p></p><p>= {nRT}_{2}\ln \left(\dfrac{{V}_{3}}{{V}_{2}}\right)</p><p></p><p>{q}_{B \to C} = {nRT}_{2}\ln \left(\dfrac{{V}_{3}}{{V}_{2}}\right)</p><p></p><p>{q}_{B \to C} = {RT}_{2}\ln \left(\dfrac{{V}_{3}}{{V}_{2}}\right) [ Sincen = 1 ]</p><p>From</p><p>FromA \to B<br/><br />{T}_{1}{V}_{1}^{\gamma - 1} = {T}_{2}{V}_{2}^{\gamma - 1}</p><p></p><p>600{V}_{1}^{\gamma - 1} = 60{V}_{2}^{\gamma - 1}</p><p></p><p>10 \times {10}^{\dfrac{5}{3} - 1} = {V}_{2}^{\gamma - 1}</p><p></p><p>{10}^{5 / 3} = {V}_{2}^{\dfrac{5}{3} - 1}</p><p></p><p>{10}^{5 / 3} = {V}_{2}^{2 / 3}</p><p></p><p>{V}_{2} = {10}^{\dfrac{5}{3} \times \dfrac{3}{2}} = 10\dfrac{5}{2}</p><p></p><p>{V}_{2} = 10\dfrac{5}{2} . . . ( 2 )<br/>Fromequation<br />From equation( 1 )<br/><br />{q}_{A \to C} = {nRT}_{2}\ln \left(\dfrac{{V}_{3}}{{V}_{2}}\right)<br/>Given,<br />Given,{q}_{A \to C} = {RT}_{2}\ln 10</p><p></p><p>{RT}_{2}\ln 10 = {RT}_{2}\ln \left(\dfrac{{V}_{3}}{{V}_{2}}\right)</p><p></p><p>\ln 10 = \ln \left(\dfrac{{V}_{3}}{{V}_{2}}\right)</p><p></p><p>\ln 10 = \ln \left(\dfrac{{V}_{3}}{10\dfrac{5}{2}}\right)</p><p></p><p>10 = \dfrac{{V}_{3}}{10\dfrac{5}{2}}</p><p></p><p>{V}_{3} = {10}^{1 + \dfrac{5}{2}} = 10\dfrac{7}{2}</p><p></p><p>2{\log V}_{3} = 2log{10}^{7 / 2} = 7

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