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JEE Advanced 2022Paper 1
Exam
JEE Advanced
Year
2022
Paper
Paper 1
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Advanced 2022 · Paper 1 · Chemistry · Thermodynamics (C)

2mol of Hg(g) is combusted in a fixed volume bomb calorimeter with...

2mol of Hg(g)iscombustedHg\left(g\right) is combusted in a fixed volume bomb calorimeter with excess of{O}_{2}atat298K and 1atmintointoHgO\left(s\right).Duringthereaction,temperatureincreasesfrom. During the reaction, temperature increases from298 . 0K to 312 . 8K.Ifheatcapacityofthebombcalorimeterandenthalpyofformationof. If heat capacity of the bomb calorimeter and enthalpy of formation ofHg\left(g\right) are 20.00kJK−1and61.32kJmol−120 . 00kJ{K}^{- 1} and 61 . 32kJ{mol}^{- 1} at 298K298K, respectively, the calculated standard molar enthalpy of formation of HgO(s)HgO\left(s\right) at 298K298K is XkJmol−1X{kJmol}^{- 1}. The value of \left|X\right|is___[Given: Gas constantR = 8 . 3J{K}^{- 1}{mol}^{- 1}]

Correct answer

0

Step-by-step solution

2Hg(g)+O2(g)⟶2HgO(s)2Hg\left(g\right) + {O}_{2}\left(g\right) ⟶ 2HgO\left(s\right)

Heat capacity of calorimeter =20kJK−1= 20kJ{K}^{- 1}

Rise in temperature =14.8K= 14 . 8K

Heat evolved =20×14.8=296kJ= 20 \times 14 . 8 = 296kJ

ΔH°=ΔU°+ΔngRT\Delta H ° = \Delta U ° + {\Delta n}_{g}RT

=−296−3×8.3×298×10−3= - 296 - 3 \times 8 . 3 \times 298 \times {10}^{- 3}

=−303.42kJ= - 303 . 42kJ

ΔH°=2ΔHf°(HgO(s))−2ΔHf°(Hg(g))\Delta H ° = 2{\Delta H}_{f} ° \left(HgO\left(s\right)\right) - 2{\Delta H}_{f} ° \left(Hg\left(g\right)\right)

−303.42=2ΔHf°(HgO(s))−2×61.32- 303 . 42 = 2{\Delta H}_{f} ° \left(HgO\left(s\right)\right) - 2 \times 61 . 32

2ΔHf°(HgO(s))=−180.78kJ2{\Delta H}_{f} ° \left(HgO\left(s\right)\right) = - 180 . 78kJ

\left|{\Delta H}_{f} ° \left(HgO\left(s\right)\right)\right| = 90 . 39kJ{mol}^{- 1}

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