Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Advanced 2013Paper 1
Exam
JEE Advanced
Year
2013
Paper
Paper 1
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Advanced 2013 · Paper 1 · Chemistry · Thermodynamics (C)

The standard enthalpies of formation of C O _ 2 ( g ) , H _ 2 O (l)...

The standard enthalpies of formation of CO2(g)C{O}_{2} ( g ) , H2O{\text{, H}}_{2} \text{O}\left(\text{l}\right)andglucose(s)atand glucose (s) at2 {5}^{\text{o}} Careare- \text{400 kJ} / \text{mol},,- \text{300 kJ} / \text{mol}andand- \text{1300 kJ} / \text{mol},respectively.Thestandardenthalpycombustionpergramofglucoseat, respectively. The standard enthalpy combustion per gram of glucose at2 {5}^{\text{o}} Cisis( \Delta{H}_{f}^{0} = - 1300kJmo{l}^{-} for\text{glucose} )

Options

  1. A+2900 kJ+ \text{2900 kJ}
  2. B−2900 kJ- \text{2900 kJ}
  3. C−16.11 kJ- \text{16.11 kJ}
  4. D+16.11 kJ+ \text{16.11 kJ}

Correct answer

C. −16.11 kJ- \text{16.11 kJ}

Step-by-step solution

Heat of combustion : It is the amount of heat evolved or absorbed (i.e. change in enthalpy) when one mole of the substance is completely burnt in air or oxygen.

Standard enthalpy of combustion of glucose reaction is given as
C6H12O6(s)+6O2(g)→6CO2(g)+6H2O(l){\text{C}}_{6} {\text{H}}_{1 2} {\text{O}}_{6 \left(\text{s}\right)} + 6 {\text{O}}_{2 \left(\text{g}\right)} \to 6 {\text{CO}}_{2 \left(\text{g}\right)} + 6 {\text{H}}_{2} \text{O} \left(\text{l}\right)
ΔHCo=ΣProductΔHfo−ΣReactantΔHfo\Delta {\text{H}}_{\text{C}}^{\text{o}} = {Σ}_{\text{Product}} \Delta {\text{H}}_{\text{f}}^{\text{o}} - {Σ}_{\text{Reactant}} \Delta {\text{H}}_{\text{f}}^{\text{o}}
={6(−400)+6(−300)}Product−{−1300×1+6×0}Reactant= {\left\{6 \left(- 4 0 0\right) + 6 \left(- 3 0 0\right)\right\}}_{\text{Product}} - {\left\{- 1 3 0 0 \times 1 + 6 \times 0\right\}}_{\text{Reactant}}
=−2400−1800+1300=−2900 kJ mole−1= - 2400 - 1800 + 1300 = - {\text{2900 kJ mole}}^{-1}
Molecular mass of glucose =72+12+96=180 g/mole= 7 2 + 1 2 + 9 6 = \text{180 g} / \text{mole}
ΔHCo/gram of glucose=−2900180=−16.11 kJ/g\Delta {\text{H}}_{\text{C}}^{\text{o}} / \text{gram of glucose} = \dfrac{- 2 9 0 0}{1 8 0} = - \text{16.11 kJ} / \text{g}.

Practice Thermodynamics (C) on Quantrex Academy →

More from Thermodynamics (C)

An ideal gas ( 0.5 mol), initially at 2 bar pressure, is compressed at a constant… JEE Advanced 2026List-I contains various physical/chemical processes, and List-II contains combinations of… JEE Advanced 2026Consider the reaction 2H_2S(g) + 3O_2(g) arrow 2H_2O(l) + 2SO_2(g) The magnitude of… JEE Main 2026Match List - I with List - II. Given V_1 and V_2 are initial and final volumes… JEE Main 2026Arrange the following isothermal processes in order of the magnitude of the work ( p - V… JEE Main 2026Consider the reaction X leftharpoons Y at 300 K. If Δ H^ θ and K are 28.40 kJ mol ^ -1… JEE Main 2026Consider the following data for the reaction X_2(g) + Y_2(g) leftharpoons 2XY(g) at 600 K… JEE Main 2026The correct order of molar heat capacities measured at 298 K and 1 bar is : JEE Main 2026 Full Thermodynamics (C) list All JEE Advanced PYQs