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JEE Main 20266 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
6 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

JEE Main 2026 · 6 April · Morning Shift · Chemistry · Alcohols Phenols and Ethers

Consider the following sequence of reactions The major product P is:

Consider the following sequence of reactions
Consider the following sequence of reactions The major product P is:
The major product P is:

Options

  1. AIf y = y (x) is the solution of the differential equation (1 + e ^ 2x )(dy)/(dx) + 2(1 + y ^ 2 ) e ^ x = 0 and y(0) = 0
  2. BIf y = y (x) is the solution of the differential equation (1 + e ^ 2x )(dy)/(dx) + 2(1 + y ^ 2 ) e ^ x = 0 and y(0) = 0
  3. CIf y = y (x) is the solution of the differential equation (1 + e ^ 2x )(dy)/(dx) + 2(1 + y ^ 2 ) e ^ x = 0 and y(0) = 0
  4. DIf y = y (x) is the solution of the differential equation (1 + e ^ 2x )(dy)/(dx) + 2(1 + y ^ 2 ) e ^ x = 0 and y(0) = 0

Correct answer

C. If y = y (x) is the solution of the differential equation (1 + e ^ 2x )(dy)/(dx) + 2(1 + y ^ 2 ) e ^ x = 0 and y(0) = 0

Step-by-step solution

Step 1: The first reagent is Cu at 573 K573\text{ K}. When a tertiary alcohol like tert-butyl alcohol is passed over heated copper at 573 K573\text{ K}, it undergoes dehydration rather than dehydrogenation to form an alkene.

(CH3)3C−OH→Cu/573 KCH2=C(CH3)2+H2O(CH_3)_3C-OH \xrightarrow{Cu / 573\text{ K}} CH_2=C(CH_3)_2 + H_2O
The intermediate product is isobutylene (2-methylpropene).

Step 2: The second set of reagents is H+H^+ and PhCOOHPhCOOH (benzoic acid). This is an acid-catalyzed addition of a carboxylic acid to an alkene, which is a standard method for synthesizing tert-butyl esters.
First, the alkene is protonated by the acid to form the most stable carbocation, which is the tertiary butyl carbocation:
CH2=C(CH3)2+H+⇌(CH3)3C+CH_2=C(CH_3)_2 + H^+ \rightleftharpoons (CH_3)_3C^+

Next, the carboxylic acid acts as a nucleophile and attacks the carbocation. The oxygen atom of the benzoic acid attacks the tert-butyl carbocation, followed by deprotonation:
PhCOOH+(CH3)3C+⇌Ph−CO−O+(H)−C(CH3)3⇌Ph−CO−O−C(CH3)3+H+PhCOOH + (CH_3)_3C^+ \rightleftharpoons Ph-CO-O^+(H)-C(CH_3)_3 \rightleftharpoons Ph-CO-O-C(CH_3)_3 + H^+

The final major product is tert-butyl benzoate. Electrophilic aromatic substitution (Friedel-Crafts alkylation) on the benzene ring does not occur here because the −COOH-COOH group is strongly deactivating, making O-alkylation (ester formation) the highly preferred pathway.

Comparing this with the given options, Option (C) represents the structure of tert-butyl benzoate.

Answer: Consider the following sequence of reactions The major product P is:
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