JEE Main 20265 AprilMorning Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 5 April
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Alcohols Phenols and Ethers
JEE Main 2026 · 5 April · Morning Shift · Chemistry · Alcohols Phenols and Ethers
One mole of phenol is treated with dilute HNO _3 at 298 K to give a...
One mole of phenol is treated with dilute HNO at K to give a mixture of products. The mixture is separated by steam distillation. The steam volatile compound (X) is separated. The increase in percentage of oxygen in (X) with respect to phenol is _____ %
(Given molar mass in g mol H:, C:, N:, O:)
(Given molar mass in g mol H:, C:, N:, O:)
Correct answer
0
Step-by-step solution
When phenol is treated with dilute at , it undergoes electrophilic aromatic substitution to give a mixture of ortho-nitrophenol and para-nitrophenol.
The mixture is separated by steam distillation. Ortho-nitrophenol is steam volatile due to intramolecular hydrogen bonding, whereas para-nitrophenol is not steam volatile due to intermolecular hydrogen bonding. Thus, the steam volatile compound (X) is ortho-nitrophenol.
Molecular formula of phenol:
Molar mass of phenol
Percentage of oxygen in phenol
Molecular formula of ortho-nitrophenol (X):
Molar mass of ortho-nitrophenol
Percentage of oxygen in ortho-nitrophenol
Increase in percentage of oxygen
We need to express this as .
Rounding to the nearest integer, we get .
Answer:
The mixture is separated by steam distillation. Ortho-nitrophenol is steam volatile due to intramolecular hydrogen bonding, whereas para-nitrophenol is not steam volatile due to intermolecular hydrogen bonding. Thus, the steam volatile compound (X) is ortho-nitrophenol.
Molecular formula of phenol:
Molar mass of phenol
Percentage of oxygen in phenol
Molecular formula of ortho-nitrophenol (X):
Molar mass of ortho-nitrophenol
Percentage of oxygen in ortho-nitrophenol
Increase in percentage of oxygen
We need to express this as .
Rounding to the nearest integer, we get .
Answer: