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JEE Main 20265 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
5 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

JEE Main 2026 · 5 April · Morning Shift · Chemistry · Alcohols Phenols and Ethers

One mole of phenol is treated with dilute HNO _3 at 298 K to give a...

One mole of phenol is treated with dilute HNO3_3 at 298298 K to give a mixture of products. The mixture is separated by steam distillation. The steam volatile compound (X) is separated. The increase in percentage of oxygen in (X) with respect to phenol is _____ ×10−1\times 10^{-1} %
(Given molar mass in g mol−1^{-1} H:11, C:1212, N:1414, O:1616)

Correct answer

0

Step-by-step solution

When phenol is treated with dilute HNO3\text{HNO}_3 at 298 K298\text{ K}, it undergoes electrophilic aromatic substitution to give a mixture of ortho-nitrophenol and para-nitrophenol.

The mixture is separated by steam distillation. Ortho-nitrophenol is steam volatile due to intramolecular hydrogen bonding, whereas para-nitrophenol is not steam volatile due to intermolecular hydrogen bonding. Thus, the steam volatile compound (X) is ortho-nitrophenol.

Molecular formula of phenol: C6H6O\text{C}_6\text{H}_6\text{O}
Molar mass of phenol =(6×12)+(6×1)+16=94 g mol−1= (6 \times 12) + (6 \times 1) + 16 = 94\text{ g mol}^{-1}
Percentage of oxygen in phenol =1694×100≈17.02%= \dfrac{16}{94} \times 100 \approx 17.02\%

Molecular formula of ortho-nitrophenol (X): C6H5NO3\text{C}_6\text{H}_5\text{NO}_3
Molar mass of ortho-nitrophenol =(6×12)+(5×1)+14+(3×16)=139 g mol−1= (6 \times 12) + (5 \times 1) + 14 + (3 \times 16) = 139\text{ g mol}^{-1}
Percentage of oxygen in ortho-nitrophenol =48139×100≈34.53%= \dfrac{48}{139} \times 100 \approx 34.53\%

Increase in percentage of oxygen =34.53%−17.02%=17.51%= 34.53\% - 17.02\% = 17.51\%

We need to express this as y×10−1%y \times 10^{-1} \%.
17.51%=175.1×10−1%17.51\% = 175.1 \times 10^{-1} \%

Rounding to the nearest integer, we get 175175.

Answer: 175175
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