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JEE Main 201912 JanuaryMorning Shift
Exam
JEE Main
Year
2019
Date
12 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Aldehydes and Ketones

JEE Main 2019 · 12 January · Morning Shift · Chemistry · Aldehydes and Ketones

The major product of the following reaction is:

The major product of the following reaction is:The major product of the following reaction is:

Options

  1. AMatch List I with List II: List I (Complexes) List II (Hybridisation) (A) [Ni ( CO ) _ 4 ] I sp ^ 3 (B) [Cu ( NH _ 3 )
  2. BMatch List I with List II: List I (Complexes) List II (Hybridisation) (A) [Ni ( CO ) _ 4 ] I sp ^ 3 (B) [Cu ( NH _ 3 )
  3. CMatch List I with List II: List I (Complexes) List II (Hybridisation) (A) [Ni ( CO ) _ 4 ] I sp ^ 3 (B) [Cu ( NH _ 3 )
  4. DMatch List I with List II: List I (Complexes) List II (Hybridisation) (A) [Ni ( CO ) _ 4 ] I sp ^ 3 (B) [Cu ( NH _ 3 )

Correct answer

A. Match List I with List II: List I (Complexes) List II (Hybridisation) (A) [Ni ( CO ) _ 4 ] I sp ^ 3 (B) [Cu ( NH _ 3 )

Step-by-step solution

Nitriles are selectively reduced by DIBAL-H to imines followed by hydrolysis to aldehydes. Similarly, esters are also reduced to aldehyde with DlBAL-HThe major product of the following reaction is:

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