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JEE Main 202429 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
29 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Biomolecules

JEE Main 2024 · 29 January · Morning Shift · Chemistry · Biomolecules

Match List I with List I List I (Substances) List II (Element...

Match List I with List I

  List I (Substances)   List II (Element Present)
A. Ziegler catalyst I. Rhodium
B. Blood Pigment II. Cobalt
C. Wilkinson catalyst III. Iron
D. Vitamin B12 IV. Titanium

Choose the correct answer from the options given below:

Options

  1. AA-II, B-IV, C-I, D-III
  2. BA-II, B-III, C-IV, D-I
  3. CA-III, B-II, C-IV, D-I
  4. DA-IV, B-III, C-I, D-II

Correct answer

D. A-IV, B-III, C-I, D-II

Step-by-step solution

Ziegler catalyst →\to Titanium

Ziegler- Natta catalyst contains two parts – a transition metal compound and an organoaluminum compound. Organoaluminum compounds contain bonds between aluminum and carbon atoms. Examples of Ziegler-Natta catalysts include TiCl4+Et3AlandTiCl3+AlEt2Cl{TiCl}_{4} + {Et}_{3}Al and {TiCl}_{3} + {AlEt}_{2}Cl. So, if we want to write the chemical formula of one of the Ziegler-Natta catalysts then it can be represented as TiCl4Al(CH3)2(CH2)2Cl{TiCl}_{4}Al ( {CH}_{3}{)}_{2} ( {CH}_{2}{)}_{2}Cl.

Blood pigment →\toIron

Haemoglobin: RBCs/erythrocytes play an important role in the transport of oxygen to various tissues. It is mainly due to the presence of an iron-containing, red-colored pigment called haemoglobin. The presence of haemoglobin gives RBCs the red colour.

Wilkinson catalyst→\toRhodium

Wilkinson's catalyst is usually obtained by treating rhodium\left(III\right)chloridehydratewithanexcessoftriphenylphosphineinrefluxingethanol.Triphenylphosphineservesasbothaligandandatwo−electronreducingagentthatoxidisesitselffromoxidationstatechloride hydrate with an excess of triphenylphosphine in refluxing ethanol. Triphenylphosphine serves as both a ligand and a two-electron reducing agent that oxidises itself from oxidation state\left(III\right)to(V)to\left(V\right).

Vitamin B12→{B}_{12} \toCobalt

Cobalt is a major part of the structure of vitamin B12B12. Therefore, if you get enough vitamin B12B12, you will also get enough cobalt. Adults need about 0.0015mg0 . 0015mg (1.51 . 5 micrograms) of vitamin B12B12 a day.

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