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JEE Main 202227 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Biomolecules

JEE Main 2022 · 27 July · Morning Shift · Chemistry · Biomolecules

Optical activity of an enantiomeric mixture is + 12 . 6 ° and the...

Optical activity of an enantiomeric mixture is +12.6°+ 12 . 6 ° and the specific rotation of (+)\left(+\right) isomer is +30°+ 30 °. The optical purity is____%

Correct answer

0

Step-by-step solution

The "optical purity" is a comparison of the optical rotation of a pure sample of unknown stereochemistry versus the optical rotation of a sample of pure enantiomer. It is expressed as a percentage. If the sample only rotates plane-polarized light half as much as expected, the optical purity is 50%.

% optical purity =observedrotationofmixture×100rotationofpureenantiomer= \dfrac{observedrotationof mixture \times 100}{rotationofpure enantiomer}

=+12.6°+30°×100=42= \dfrac{+ 12 . 6 °}{+ 30 °} \times 100 = 42

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