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JEE Main 202120 JulyEvening Shift
Exam
JEE Main
Year
2021
Date
20 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

JEE Main 2021 · 20 July · Evening Shift · Chemistry · Carboxylic Acid Derivatives

The correct order of their reactivity towards hydrolysis at room...

The correct order of their reactivity towards hydrolysis at room temperature is:

The correct order of their reactivity towards hydrolysis at room temperature is:

Options

  1. A(A)>(B)>(C)>(D)( A ) > ( B ) > ( C ) > ( D )
  2. B(D)>(A)>(B)>(C)( D ) > ( A ) > ( B ) > ( C )
  3. C(D)>(B)>(A)>(C)( D ) > ( B ) > ( A ) > ( C )
  4. D(A)>(C)>(B)>(D)( A ) > ( C ) > ( B ) > ( D )

Correct answer

A. (A)>(B)>(C)>(D)( A ) > ( B ) > ( C ) > ( D )

Step-by-step solution

+M+ M group attached with carbonyl bond will decrease reactivity of acid derivative towards hydrolysis. For halogen −I- I dominate over +M+ M therefore, acid chloride is most reactive. As extent of +M+ M effect increases, reactivity decreases. Overall, order of reactivity is:The correct order of their reactivity towards hydrolysis at room temperature is:
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